Počet záznamů: 1

Oxidatively Induced Concurrent Cationic and Radical Polymerization of Isobutylene in the Presence of LiCB(11)Me(12)

  1. 1.
    0361440 - UOCHB-X 2012 RIV US eng J - Článek v odborném periodiku
    Volkis, V. - Douvris, C. - Michl, Josef
    Oxidatively Induced Concurrent Cationic and Radical Polymerization of Isobutylene in the Presence of LiCB(11)Me(12).
    Journal of the American Chemical Society. Roč. 133, č. 20 (2011), s. 7801-7809 ISSN 0002-7863
    Grant ostatní: NSF(US) CHE-0715374
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: permethylated icosahedral anion CB11Me12 * concurrent cationic and radical polymerization of isobutylene
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 9.907, rok: 2011

    Concurrent cationic and radical polymerization of isobutylene in presence of LiCB11Me12 anion is described. Mechanistic explanation of polymerization is discused on the base of influnce of lithium salt of permethylated icosahedral anion CB11Me12-. A closer investigation confirmed that, in the presence of LiCB11Me12 in weakly coordinating solvents radical polymerization of isobutylene takes place.
    Trvalý link: http://hdl.handle.net/11104/0198751