Počet záznamů: 1

Stereoselective Synthesis of (E)-alpha-Fluorovinylphosphonates from alpha,alpha-Difluorophosphonates

  1. 1.
    0360958 - UOCHB-X 2012 RIV DE eng J - Článek v odborném periodiku
    Cherkupally, Prabhakar - Slazhnev, Anton - Beier, Petr
    Stereoselective Synthesis of (E)-alpha-Fluorovinylphosphonates from alpha,alpha-Difluorophosphonates.
    Synlett. -, č. 3 (2011), s. 331-334 ISSN 0936-5214
    Grant CEP: GA ČR GP203/08/P310
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: phosphonate * fluorine * elimination
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 2.710, rok: 2011

    alpha,alpha-Difluorophosphonates, which are readily available from alkyl halides and diethyl difluoromethylphosphonate, undergo elimination of hydrogen fluoride using alkali metal alkoxides to provide alpha-fluorovinylphosphonates in high yields and E/Z selectivities.
    Trvalý link: http://hdl.handle.net/11104/0198389