Počet záznamů: 1

Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids

  1. 1.
    0360102 - UOCHB-X 2012 RIV GB eng J - Článek v odborném periodiku
    Henke, Adam - Šrogl, Jiří
    Pd2+ and Cu2+ catalyzed oxidative cross-coupling of mercaptoacetylenes and arylboronic acids.
    Chemical Communications. Roč. 47, č. 14 (2011), s. 4282-4284 ISSN 1359-7345
    Grant CEP: GA ČR GA203/08/1318
    Grant ostatní: AV ČR(CZ) M200550908
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: mercaptoacetylenes * oxidative cross-coupling * Cu/Pd catalysis
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 6.169, rok: 2011

    An oxidative thiolate scavenging concept in a metal catalyzed reaction is presented and demonstrated on the aerobic Pd and Cu catalyzed cross-coupling of mercaptoacetylenes with arylboronic acids. Synthetic value of the chemistry as the complementary tool to the Sonogashira protocol has been demonstrated on a series of functionalized mercaptoacetylene substrates.
    Trvalý link: http://hdl.handle.net/11104/0197734