Počet záznamů: 1

Theoretical study on the complexation of the cesium cation with dibenzo-18-crown-6

  1. 1.
    0359586 - UMCH-V 2012 RIV AT eng J - Článek v odborném periodiku
    Toman, Petr - Makrlík, E. - Vaňura, P.
    Theoretical study on the complexation of the cesium cation with dibenzo-18-crown-6.
    Monatshefte fur Chemie. Roč. 142, č. 6 (2011), s. 569-571 ISSN 0026-9247
    Grant CEP: GA ČR(CZ) GAP205/10/2280
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: crown ethers * macrocycles * complexation
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 1.532, rok: 2011

    By using quantum mechanical calculations, the most probable structures of free dibenzo-18-crown-6 ligand and the cationic complex species of Cs+ both with one and with two dibenzo-18-crown-6 ligands were derived. In these two complexes, the ‘‘central’’ cation Cs+ is bound by strong bond interactions to the corresponding ethereal oxygen atoms of the parent crown ligand.
    Trvalý link: http://hdl.handle.net/11104/0006444