Počet záznamů: 1

Experimental and theoretical study of the complexation of the thallium cation with a hexaarylbenzene-based receptor

  1. 1.
    0359318 - UMCH-V 2012 RIV AT eng J - Článek v odborném periodiku
    Makrlík, E. - Toman, Petr - Vaňura, P. - Rathore, R.
    Experimental and theoretical study of the complexation of the thallium cation with a hexaarylbenzene-based receptor.
    Monatshefte fur Chemie. Roč. 142, č. 5 (2011), s. 447-451 ISSN 0026-9247
    Grant CEP: GA ČR(CZ) GAP205/10/2280
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: receptors * macrocycles * complexation
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 1.532, rok: 2011

    From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of a hexaarylbenzene-based receptor. Tl+ complex species dissolved in nitrobenzene saturated with water was determined. By using the quantum-mechanical density functional level of theory calculations, the most probable structure of this complex was derived.
    Trvalý link: http://hdl.handle.net/11104/0006439