Počet záznamů: 1
Experimental and theoretical study of the complexation of the thallium cation with a hexaarylbenzene-based receptor
- 1.0359318 - ÚMCH 2012 RIV AT eng J - Článek v odborném periodiku
Makrlík, E. - Toman, Petr - Vaňura, P. - Rathore, R.
Experimental and theoretical study of the complexation of the thallium cation with a hexaarylbenzene-based receptor.
Monatshefte fur Chemie. Roč. 142, č. 5 (2011), s. 447-451. ISSN 0026-9247. E-ISSN 1434-4475
Grant CEP: GA ČR(CZ) GAP205/10/2280
Výzkumný záměr: CEZ:AV0Z40500505
Klíčová slova: receptors * macrocycles * complexation
Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
Impakt faktor: 1.532, rok: 2011
From extraction experiments in the two-phase water/nitrobenzene system and γ-activity measurements, the stability constant of a hexaarylbenzene-based receptor. Tl+ complex species dissolved in nitrobenzene saturated with water was determined. By using the quantum-mechanical density functional level of theory calculations, the most probable structure of this complex was derived.
Trvalý link: http://hdl.handle.net/11104/0006439
Počet záznamů: 1