Počet záznamů: 1

The first (tricarbollide)rhodium halide complexes

  1. 1.
    0358361 - UACH-T 2012 RIV NL eng J - Článek v odborném periodiku
    Loginov, D.A. - Starikova, ZA. - Petrovskii, PV. - Holub, Josef - Kudinov, AR.
    The first (tricarbollide)rhodium halide complexes.
    Inorganic Chemistry Communications. Roč. 14, č. 1 (2011), s. 313-315 ISSN 1387-7003
    Grant CEP: GA MŠk LC523
    Výzkumný záměr: CEZ:AV0Z40320502
    Klíčová slova: boranes * metallacarboranes * rhodium * tricarbollide
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 1.972, rok: 2011

    Reactions of (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh(cod) with Br-2 or I-2 give complexes [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10) RhX2](2) (X=Br (2a), I (2b)). Reaction of 2b with TIBF4 affords cation [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10)(2)Rh-2(mu-I)(3)](+) (3). Complex 2a reacts with Tl[Tl(eta-7,8-C2B9H11)] giving the bis(carborane) complex (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh (eta-7,8-C2B9H11) (4). Structures of 2a,b were determined by X-ray diffraction.
    Trvalý link: http://hdl.handle.net/11104/0196433