Počet záznamů: 1

Charge distribution within hypercarbon-halogenated 1-Ph-2-X-1,2-dicarba-closo-dodecaboranes, (X = F, Cl, Br, I): A dipole moment and computational study

  1. 1.
    0357021 - UACH-T 2011 RIV NL eng J - Článek v odborném periodiku
    Hnyk, Drahomír - Všetečka, V. - Drož, L.
    Charge distribution within hypercarbon-halogenated 1-Ph-2-X-1,2-dicarba-closo-dodecaboranes, (X = F, Cl, Br, I): A dipole moment and computational study.
    Journal of Molecular Structure. Roč. 978, 1-3 (2010), s. 246-249 ISSN 0022-2860
    Grant CEP: GA MŠk LC523
    Výzkumný záměr: CEZ:AV0Z40320502
    Klíčová slova: halogens * carboranes * dipole moments
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 1.599, rok: 2010

    Vector analyses of experimental dipole moments of a series of halogenated 1-Ph-2-X-1,2-dicarba-closo-dodecaboranes, (X = F, Cl, Br, I) combined with theoretical calculations show that there are intramolecular contacts between heavy halogens (Br and I) and the benzene ring, whereas this attraction is absent for F and Cl. (C) 2010 Elsevier B.V. All rights reserved.
    Trvalý link: http://hdl.handle.net/11104/0006364