Počet záznamů: 1

New building block for organometallic-inorganic hybrid polymers: the mixed group 15/16 element ligand complex [Cp*.sub.2./sub.Mo.sub.2./sub.(μ,η.sup.2:2./sup.-PSe).sub.2./sub.(μ-Se)](Cp* = C.sub.5./sub.Me.sub.5./sub.)

  1. 1.
    0356248 - FZU-D 2011 RIV DE eng J - Článek v odborném periodiku
    Bodensteiner, M. - Dušek, Michal - Kubicki, M. M. - Pronold, M. - Scheer, M. - Wachter, J. - Zabel, M.
    New building block for organometallic-inorganic hybrid polymers: the mixed group 15/16 element ligand complex [Cp*2Mo2(μ,η2:2-PSe)2(μ-Se)](Cp* = C5Me5).
    European Journal of Inorganic Chemistry. Roč. 2010, č. 33 (2010), s. 5298-5303 ISSN 1434-1948
    Výzkumný záměr: CEZ:AV0Z10100521
    Klíčová slova: phosphorus * selenium * copper * coordination modes * polymers
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 2.909, rok: 2010

    The synthesis and spectroscopic characterization of [Cp*2Mo2P2Se3] (Cp* = C5Me5) and its use as a molecular building block in the formation of copper(I) halide polymers is described. The following new compounds were described: [(Cp*2Mo2P2Se3)2(CuBr)2], [(Cp*2Mo2P2Se3)(CuI)3(CH3CN)]n (two isomeric forms one of them being incommensurate) and [(Cp*2Mo2P2Se3)(P4Se3)(CuI)2]n.
    Trvalý link: http://hdl.handle.net/11104/0194821