Počet záznamů: 1

Synthesis of Mono(perfluoroalkyl) Cyclodextrins via Cross Metathesis

  1. 1.
    0355716 - UOCHB-X 2011 RIV DE eng J - Článek v odborném periodiku
    Řezanka, M. - Eignerová, Barbara - Jindřich, J. - Kotora, M.
    Synthesis of Mono(perfluoroalkyl) Cyclodextrins via Cross Metathesis.
    European Journal of Organic Chemistry. -, č. 32 (2010), s. 6256-6262 ISSN 1434-193X
    Grant CEP: GA AV ČR KAN200200651
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: metathesis * cyclodextrins * fluorine * alkylation * amphiphiles
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 3.206, rok: 2010

    Ruthenium–carbene complex catalyzed cross metathesis of monoallyl alpha-, beta-, and gamma-cyclodextrins with perfluoroalkylpropenes resulted in the formation of the corresponding perfluoroalkylated cyclodextrins. The reactions proceeded under standard reaction conditions and yielded the desired compounds in reasonable yields. Dynamic light scattering measurements proved the ability of the prepared compounds to aggregate in water solution forming nanoparticles in the range of tens and thousands of nanometers.
    Trvalý link: http://hdl.handle.net/11104/0194418