Počet záznamů: 1

Synthesis and Electrochemistry of Cyclopentadienyl Ferratricarbollides Substituted by Me and Ph Groups on the Cage Carbon Atoms

  1. 1.
    0352913 - UACH-T 2011 RIV DE eng J - Článek v odborném periodiku
    Holub, Josef - Bakardjiev, Mario - Štíbr, Bohumil - Štěpnička, P. - Císařová, I.
    Synthesis and Electrochemistry of Cyclopentadienyl Ferratricarbollides Substituted by Me and Ph Groups on the Cage Carbon Atoms.
    European Journal of Inorganic Chemistry. -, č. 26 (2010), s. 4196-4200 ISSN 1434-1948
    Grant CEP: GA MŠk LC523
    Výzkumný záměr: CEZ:AV0Z40320502
    Klíčová slova: Iron * boron * carboranes
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 2.909, rok: 2010

    Neutral tricarbollide tautomers of general formula 7-tBuNH-8,9-R,R’-nido-7,8,9-C3B8H9 generated a series of very stable, twelve-vertex ferratricarbollides. Electrochemical studies revealed that the FeII/FeIII redox potentials are primarily affected by the type of the ferratricarbaborane cage and, to a lesser extent, by the Me and Ph substituents residing on the cage carbon atoms.
    Trvalý link: http://hdl.handle.net/11104/0192300