Zirconium doped nano-dispersed oxides of Fe, Al and Zn for destruction of warfare agents

0350848 - ÚACH 2011 RIV US eng J - Článek v odborném periodiku
Štengl, Václav - Houšková, Vendula - Bakardjieva, Snejana - Murafa, Nataliya - Maříková, Monika - Opluštil, F. - Němec, T.
Zirconium doped nano-dispersed oxides of Fe, Al and Zn for destruction of warfare agents.
Materials Characterization. Roč. 61, č. 11 (2010), s. 1080-1088. ISSN 1044-5803. E-ISSN 1873-4189
Výzkumný záměr: CEZ:AV0Z40320502
Klíčová slova: warfare agents * nano-dispersed oxides * homogeneous hydrolysis
Kód oboru RIV: CA - Anorganická chemie
Impakt faktor: 1.496, rok: 2010

Zirconium doped nano dispersive oxides of Fe, Al and Zn were prepared by a homogeneous hydrolysis of the respective sulfate salts with urea in aqueous solutions. Synthesized metal oxide hydroxides were characterized using Brunauer–Emmett–Teller (BET) surface area and Barrett–Joiner–Halenda porosity (BJH), X-ray diffraction (XRD), infrared spectroscopy (IR), scanning electron microscopy (SEM) and energy-dispersive X-ray microanalysis (EDX). These oxides were taken for an experimental evaluation of their reactivity with sulfur mustard (HD or bis(2-chloroethyl)sulfide), soman (GD or (3,3′-Dimethylbutan-2-yl)-methylphosphonofluoridate) and VX agent (S-[2-(diisopropylamino)ethyl]-O-ethyl-methylphosphonothionate).
Trvalý link: http://hdl.handle.net/11104/0190738