Počet záznamů: 1  

How to elucidate and control the redox sequence in vinylbenzoate and vinylpyridine bridged diruthenium complexes

  1. 1.
    0349519 - ÚFCH JH 2011 RIV GB eng J - Článek v odborném periodiku
    Pevny, F. - Winter, R. F. - Sarkar, B. - Záliš, Stanislav
    How to elucidate and control the redox sequence in vinylbenzoate and vinylpyridine bridged diruthenium complexes.
    Dalton Transactions. Roč. 39, č. 34 (2010), s. 8000-8011. ISSN 1477-9226. E-ISSN 1477-9234
    Grant CEP: GA AV ČR KAN100400702; GA MŠMT 1P05OC068; GA MŠMT OC09043
    Výzkumný záměr: CEZ:AV0Z40400503
    Klíčová slova: vinylbenzoate-bridged diruthenium complexes * electrochemistry * vinylpyridine-bridged diruthenium complexes
    Kód oboru RIV: CG - Elektrochemie
    Impakt faktor: 3.647, rok: 2010

    Vinylbenzoate-bridged diruthenium complexes (RHCdouble bond, length as m-dashCH)(CO)(PiPr3)2Ru(μ-4-OOCC6H4–CHdouble bond, length as m-dashCH)RuCl(CO)(PiPr3)2 (R = Ph, 3a or CF3, 3b) and vinylpyridine-bridged (η6-p-cymene)Cl2Ru(μ-NC5H4-4-CHdouble bond, length as m-dashCH)RuCl(CO)(PiPr3)2 (3c) have been prepared from their monoruthenium precursors and investigated with respect to the sequence of the individual redox steps and electron delocalization in their partially and fully oxidized states. Identification of the primary redox sites rests on the trends in redox potentials and the EPR, IR and Vis/NIR signatures of the oxidized radical cations and is correctly reproduced by quantum chemical investigations.
    Trvalý link: http://hdl.handle.net/11104/0189735

     
     
Počet záznamů: 1  

  Tyto stránky využívají soubory cookies, které usnadňují jejich prohlížení. Další informace o tom jak používáme cookies.