Počet záznamů: 1

Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid

  1. 1.
    0348376 - UFCH-W 2011 RIV NL eng J - Článek v odborném periodiku
    Langmaier, Jan - Trojánek, Antonín - Samec, Zdeněk
    Electron transfer across the polarized interface between water and a hydrophobic redox-active ionic liquid.
    Electrochemistry Communications. Roč. 12, č. 10 (2010), s. 1333-1335 ISSN 1388-2481
    Grant CEP: GA MŠk ME08098; GA ČR GAP206/10/1231
    Výzkumný záměr: CEZ:AV0Z40400503
    Klíčová slova: redox-active ionic liquid * membrane * cyclic voltammetry
    Kód oboru RIV: CG - Elektrochemie
    Impakt faktor: 4.282, rok: 2010

    Here we report the synthesis of a new redox-active ionic liquid (IL), (ferrocenylmethyl)dodecyldimethylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate that can be used to form the polarizable water│IL interface at an elevated temperature (43 °C). Experimental approach is based on the cyclic voltammetry of the charge transfer processes occurring at the IL membrane supported on a thin microporous filter. Evidence is provided of the interfacial electron transfer between the ferrocenated cation of IL and an electron acceptor, IrCl62−, in the adjacent aqueous phase.
    Trvalý link: http://hdl.handle.net/11104/0188926