Počet záznamů: 1

Preferential activation of primary C–H bonds in the reactions of small alkanes with the diatomic MgO+. cation

  1. 1.
    0345734 - UOCHB-X 2011 RIV DE eng J - Článek v odborném periodiku
    Schröder, Detlef - Roithová, J. - Alikhani, E. - Kwapien, K. - Sauer, J.
    Preferential activation of primary C–H bonds in the reactions of small alkanes with the diatomic MgO+. cation.
    Chemistry - A European Journal. Roč. 16, č. 13 (2010), s. 4110-4119 ISSN 0947-6539
    Grant CEP: GA AV ČR KJB400550704; GA ČR GA203/08/1487
    Grant ostatní: ERC(XE) HORIZOMS AdG226373
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: alkanes * C-H activation * density functional calculations * magnesium oxide
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 5.476, rok: 2010

    The C-H bond activation of small alkanes by the gaseous MgO+ cation is probed by mass spectrometric methods. In the initial step, a pronounced kinetic control leads to the preferential attack of primary C-H bonds.
    Trvalý link: http://hdl.handle.net/11104/0186937