Počet záznamů: 1

White-emitting oxidized silicon nanocrystals: Discontinuity in spectral development with reducing size

  1. 1.
    0343173 - FZU-D 2011 RIV US eng J - Článek v odborném periodiku
    Dohnalová, Kateřina - Ondič, Lukáš - Kůsová, Kateřina - Pelant, Ivan - Rehspringer, J.L. - Mafouana, R.-R.
    White-emitting oxidized silicon nanocrystals: Discontinuity in spectral development with reducing size.
    Journal of Applied Physics. Roč. 107, č. 5 (2010), 053102/1-053102/6 ISSN 0021-8979
    Grant CEP: GA AV ČR(CZ) IAA101120804; GA MŠk LC510; GA AV ČR KJB100100903; GA ČR GA202/07/0818
    Výzkumný záměr: CEZ:AV0Z10100521
    Klíčová slova: silicon nanocrystals * luminescence * spectral shift
    Kód oboru RIV: BM - Fyzika pevných látek a magnetismus
    Impakt faktor: 2.064, rok: 2010

    Small oxidized silicon nanocrystals of average sizes below 3.5 nm are prepared using modified electrochemical etching of a silicon wafer. Modifications introduced in the etching procedure together with postetching treatment in H2O2 lead to a decrease in the nanocrystalline core size and also, to some extent, to changes in the surface oxide. The interplay between these two factors allows us to blueshift the photoluminescence (PL) spectrum from 680 down to 590 nm, which is accompanied by changes in PL dynamics. This continual development, however, stops at about 590 nm, below which abrupt switching to fast decaying blue emission band at about 430 nm was observed. Discontinuity of the spectral shift and possible relation between both bands are discussed.
    Trvalý link: http://hdl.handle.net/11104/0185707