Počet záznamů: 1

Synthesis of thermally responsive cylindrical molecular brushes via a combination of nitroxide-mediated radical polymerization and “grafting onto” strategy

  1. 1.
    0341122 - UMCH-V 2010 RIV GB eng J - Článek v odborném periodiku
    Gromadzki, Daniel - Jigounov, Alexander - Štěpánek, Petr - Makuška, R.
    Synthesis of thermally responsive cylindrical molecular brushes via a combination of nitroxide-mediated radical polymerization and “grafting onto” strategy.
    European Polymer Journal. Roč. 46, č. 4 (2010), s. 804-813 ISSN 0014-3057
    Grant CEP: GA ČR GA202/09/2078
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: nitroxide-mediated radical polymerization * grafting onto * thermally responsive cylindrical brushes
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 2.518, rok: 2010

    It was demonstrated that the combination of nitroxide-mediated radical polymerization and "grafting onto" Williamson etherification reaction can be successfully used for the synthesis of loosely grafted amphiphilic molecular brushes. The amphiphilic behavior of molecular brush PS-MPEG was validated by 1H NMR spectroscopy in solvents selective for the respective hydrophobic and hydrophilic segments.
    Trvalý link: http://hdl.handle.net/11104/0005796