Počet záznamů: 1

HOST-GUEST INTERACTION OF PESTICIDE BIFENOX WITH CYCLODEXTRIN MOLECULES. AN ELECTROCHEMICAL STUDY

  1. 1.
    0341088 - UFCH-W 2010 RIV CZ eng J - Článek v odborném periodiku
    Hromadová, Magdaléna - Sokolová, Romana - Pospíšil, Lubomír - Lachmanová, Štěpánka - Fanelli, N. - Giannarelli, S.
    HOST-GUEST INTERACTION OF PESTICIDE BIFENOX WITH CYCLODEXTRIN MOLECULES. AN ELECTROCHEMICAL STUDY.
    Collection of Czechoslovak Chemical Communications. Roč. 74, 11-12 (2009), s. 1647-1664 ISSN 0010-0765
    Grant CEP: GA AV ČR IAA400400802; GA ČR GA203/08/1157; GA ČR GA203/09/0705; GA ČR GA203/09/1607; GA MŠk LC510; GA MŠk OC 140
    Výzkumný záměr: CEZ:AV0Z40400503
    Klíčová slova: reductions * electroreduction * nitro anion radical * electrochemistry
    Kód oboru RIV: CG - Elektrochemie
    Impakt faktor: 0.856, rok: 2009

    The reduction of nitroaromatic compound bifenox (methyl 5-(2,4-dichlorophenoxy)-2-nitrobenzoate) was studied in aprotic solvents in the absence or presence of cyclodextrin (CD) molecules of different cavity sizes. beta CD and gamma CD form complexes with bifenox in DMSO with the complex formation constants (5 +/- 2) x 10(2) M-1 [beta CD-bifenox] and (3 +/- 1) x 10(2) M-1 [gamma CD -bifenox], respectively. Bifenox yields a relatively stable anion radical in dimethyl sulfoxide, which is further reduced at more negative potentials by an overall addition of three electrons and four protons to the corresponding phenylhydroxylamine. In the presence of beta CD the first reduction wave of bifenox becomes irreversible, it is shifted towards more positive potentials and the uptake of more than one electron is observed (up to four electrons during the exhaustive electrolysis).
    Trvalý link: http://hdl.handle.net/11104/0184182