Počet záznamů: 1

Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(2)Fe](2+) cations

  1. 1.
    0340428 - UACH-T 2010 RIV US eng J - Článek v odborném periodiku
    Štíbr, Bohumil - Bakardjiev, Mario - Holub, Josef - Růžička, A. - Kvíčalová, Magdalena
    Systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into carborane cages via [(eta(6)-arene)Fe](2+) dications. A series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] complexes. Reliable synthesis of polymethylated [(eta(6)-arene)(2)Fe](2+) cations.
    Inorganic Chemistry. Roč. 48, č. 23 (2009), s. 10904-10906 ISSN 0020-1669
    Grant CEP: GA MŠk LC523
    Výzkumný záměr: CEZ:AV0Z40320502
    Klíčová slova: organotransition-metal matallacarborane * magnetic-resonance spectroscopy * iron complexes
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 4.657, rok: 2009

    Developed was a systematic method for the incorporation of the {(eta(6)-arene)Fe} fragment into a carborane cage. Reactions between [(eta(6)-arene)(2)Fe](PF6)(2) salts and Tl-2[nido-7,8-C2B9H11] in refluxing (CH2)(2)Cl-2 generated a series of [3-(eta(6)-arene)-closo-3,1,2-FeC2B9H11] neutral complexes with variable types of polymethylated arene ligands in the structure. The structures of durene and hexamethylbenzene complexes were established by X-ray diffraction analyses. The work also shows that the original hi temperature method for the preparation of the [(eta(6)-arene)(2)Fe](2+) dications fails for mesitylene and durene compounds, which was overcome by a reliable room-temperature modification.
    Trvalý link: http://hdl.handle.net/11104/0005774