Počet záznamů: 1

Alkyne-promoted H-2 loss in a metallaborane: nido-to-closo cluster transformation and sp C-H Bbnd oxidative addition

  1. 1.
    0340321 - UACH-T 2010 RIV DE eng J - Článek v odborném periodiku
    Álvarez, A. - Macias, R. - Bould, Jonathan - Cunchillos, C. - Lahoz, F.J. - Oro, L.A.
    Alkyne-promoted H-2 loss in a metallaborane: nido-to-closo cluster transformation and sp C-H Bbnd oxidative addition.
    Chemistry - A European Journal. Roč. 15, č. 22 (2009), s. 5428-5431 ISSN 0947-6539
    Grant CEP: GA AV ČR(CZ) IAA400320601
    Výzkumný záměr: CEZ:AV0Z40320502
    Klíčová slova: alkyne ligands * boranes * cluster compounds
    Kód oboru RIV: CA - Anorganická chemie
    Impakt faktor: 5.382, rok: 2009

    The proposed catalytic cycle involves a full cluster participation with the matallacarborane cluster acting both as a source and a sinj for electrons and for dihydrogen trough nido-closo-nido cluster transformations.
    Trvalý link: http://hdl.handle.net/11104/0183588