Počet záznamů: 1

ATRP of 2-vinylpyridine and tert-butyl acrylate mixtures giving precursors of polyampholytes

  1. 1.
    0339573 - UMCH-V 2010 RIV US eng J - Článek v odborném periodiku
    Čadová, Eva - Konečný, Jiří - Kříž, Jaroslav - Svitáková, Romana - Holler, Petr - Genzer, J. - Vlček, Petr
    ATRP of 2-vinylpyridine and tert-butyl acrylate mixtures giving precursors of polyampholytes.
    Journal of Polymer Science. Part A - Polymer Chemistry. Roč. 48, č. 3 (2010), s. 735-741 ISSN 0887-624X
    Grant CEP: GA MŠk 1P05ME753
    Výzkumný záměr: CEZ:AV0Z40500505
    Klíčová slova: atom transfer radical polymerization (ATRP) * copolymerization * polyelectrolytes
    Kód oboru RIV: CD - Makromolekulární chemie
    Impakt faktor: 3.894, rok: 2010

    Statistical copolymers of 2-vinylpyridine and tert-butyl acrylate were first synthesized by ATRP using methyl 2-bromopropanoate/CuCl/Me4Cyclam system and transformed to ampholytic poly(2-vinylpyridine-co-acrylic acid). Monomer reactivity ratios of 2-VPy and t-BuA were determined by extended Kelen-Tüdos method and by COPOINT program on the basis of NMR spectra and elemental analysis of the prepared copolymers.
    Trvalý link: http://hdl.handle.net/11104/0005739