Počet záznamů: 1

New Lipophilic 2-Amino-N,N’-dialkyl-4,5-dimethylimidazolium Cations: Synthesis, Structure, Properties, and Outstanding Thermal Stability in Alkaline Media

  1. 1.
    0333016 - UOCHB-X 2010 RIV DE eng J - Článek v odborném periodiku
    Kunetskiy, Roman Alexejevič - Císařová, I. - Šaman, David - Lyapkalo, Ilya
    New Lipophilic 2-Amino-N,N’-dialkyl-4,5-dimethylimidazolium Cations: Synthesis, Structure, Properties, and Outstanding Thermal Stability in Alkaline Media.
    Chemistry - A European Journal. Roč. 15, č. 37 (2009), s. 9477-9485 ISSN 0947-6539
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: aromatic stabilization * imidazolium cations * lipophilicity * phase-transfer catalysis
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 5.382, rok: 2009

    Efforts have been directed towards augmenting the stability and base resistance of substituted imidazolium cations through judicious combination of electronic and steric effects. By applying this design principle, novel imidazolium cations have been obtained that display exceptional robustness under strongly basic conditions at high temperatures.
    Trvalý link: http://hdl.handle.net/11104/0178105