Methyl 4-toluenesulfonyloxymethylphosphonate, a new and versatile reagent for the convenient synthesis of phosphonate-containing compounds

0332679 - ÚOCHB 2010 RIV GB eng J - Článek v odborném periodiku
Markusová Kóšiová, Ivana - Točík, Zdeněk - Buděšínský, Miloš - Šimák, Ondřej - Liboska, Radek - Rejman, Dominik - Pačes, Ondřej - Rosenberg, Ivan
Methyl 4-toluenesulfonyloxymethylphosphonate, a new and versatile reagent for the convenient synthesis of phosphonate-containing compounds.
Tetrahedron Letters. Roč. 50, č. 49 (2009), s. 6745-6747. ISSN 0040-4039. E-ISSN 1873-3581
Grant CEP: GA ČR GA202/09/0193; GA ČR GA203/09/0820; GA MŠMT(CZ) LC06061; GA MŠMT(CZ) LC06077; GA AV ČR KAN200520801
Výzkumný záměr: CEZ:AV0Z40550506
Klíčová slova: nucleoside phosphonates * phosphonylation * methyl 4-toluenesulfonyloxymethylphosphonate
Kód oboru RIV: CC - Organická chemie
Impakt faktor: 2.660, rok: 2009

A convenient procedure leading to new phosphonylating reagent, requiring no chromatographic purification, is described. This stable reagent is efficient in phosphonylations and causes no unwanted methylation in nucleoside molecule.
Trvalý link: http://hdl.handle.net/11104/0177860