Počet záznamů: 1

Combined FT-IR Spectroscopic and DFT Theoretical Study on Carbon Dioxide Adsorption on the Zeolite H-FER

  1. 1.
    0331337 - UOCHB-X 2011 RIV GB eng J - Článek v odborném periodiku
    Pulido, A. - Delgado, M. R. - Bludský, Ota - Rubeš, Miroslav - Nachtigall, Petr - Areán, C. O.
    Combined FT-IR Spectroscopic and DFT Theoretical Study on Carbon Dioxide Adsorption on the Zeolite H-FER.
    Energy & Environmental Science. Roč. 2, č. 11 (2009), s. 1187-1195 ISSN 1754-5692
    Grant CEP: GA ČR GA203/09/0143; GA MŠk LC512
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: DFT * FTIR
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 8.500, rok: 2009

    Adsorption complexes on isolated Si(OH)Al Bronsted acid sites involve an adsorption enthalpy (deltaH0) in the range of -33 to -36 kJ mol-1, about half of which is due to the weak intermolecular interactions between CO2 and zeolite framework. Calculated adsorption enthalpies are in good agreement with the experimentally found value of delta H0 = -30 kJ mol-1.
    Trvalý link: http://hdl.handle.net/11104/0176874