Počet záznamů: 1

Large Effect of a Small Substitution: Competition of Dehydration with Charge Retention and Coulomb Explosion in Gaseous [(bipyR)Au(.mu.-O)2Au(bipyR)]2+ Dications

  1. 1.
    0330043 - UOCHB-X 2010 RIV US eng J - Článek v odborném periodiku
    Tyo, E. C. - Castleman Jr., A. W. - Schröder, Detlef - Milko, Petr - Roithová, J. - Ortega, J. M. - Cinellu, M. A. - Cocco, F. - Minghetti, G.
    Large Effect of a Small Substitution: Competition of Dehydration with Charge Retention and Coulomb Explosion in Gaseous [(bipyR)Au(.mu.-O)2Au(bipyR)]2+ Dications.
    Journal of the American Chemical Society. Roč. 131, č. 36 (2009), s. 13009-13019 ISSN 0002-7863
    Grant CEP: GA AV ČR KJB400550704; GA ČR GA203/08/1487
    Grant ostatní: EPITOPES(XE) 15637
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: dications * electrospray ionization * gold cluster * gold oxide
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 8.580, rok: 2009

    Dinuclear gold(III) clusters with a rhombic Au2O2 core and substituted 2,2'-bipyridyl ligands are examined by tandem mass spectrometry. The fragmentation behavior of the mass-selected dications reveals an exceptionally pronounced effect of substitution.
    Trvalý link: http://hdl.handle.net/11104/0175916