Počet záznamů: 1

Thermodynamic and Structural Investigations on the Complexation Process of Dioxo Macrocyclic Ligands: Towards Neutral Copper Complexes at Physiological pH

  1. 1.
    0328120 - UOCHB-X 2010 RIV DE eng J - Článek v odborném periodiku
    Déchamps-Olivier, I. - Cadiou, C. - Harakat, D. - Roisnel, T. - Chuburu, F. - Hodačová, J. - Koščová, Simona
    Thermodynamic and Structural Investigations on the Complexation Process of Dioxo Macrocyclic Ligands: Towards Neutral Copper Complexes at Physiological pH.
    European Journal of Inorganic Chemistry. -, č. 20 (2009), s. 2929-2941 ISSN 1434-1948
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: macrocyclic ligands * thermodynamics * UV * copper
    Kód oboru RIV: CC - Organická chemie
    Impakt faktor: 2.941, rok: 2009

    Protonation and the overall complexation constants of copper(II) complexes of two dioxotetraza mono- and two bis-macrocycles were determined by potentiometry. Complexation sequence was elucidated for each ligand by means of UV/Vis and EPR spectroscopy. According to the ligand structure, two complexation mechanisms can be characterized.
    Trvalý link: http://hdl.handle.net/11104/0174513