Počet záznamů: 1

Platinum(II)-mediated dehydrosulfurization and oxidative carbon-carbon coupling in the gas-phase decomposition of thioethers

  1. 1.
    0326524 - UOCHB-X 2010 RIV NL eng J - Článek v odborném periodiku
    Butschke, B. - Schlangen, M. - Schröder, Detlef - Schwarz, H.
    Platinum(II)-mediated dehydrosulfurization and oxidative carbon-carbon coupling in the gas-phase decomposition of thioethers.
    International Journal of Mass Spectrometry. Roč. 283, č. 1 (2009), s. 3-8 ISSN 1387-3806
    Výzkumný záměr: CEZ:AV0Z40550506
    Klíčová slova: bond activation * bond formation * platinum chemistry * reaction mechanisms * thio ethers
    Kód oboru RIV: CF - Fyzikální chemie a teoretická chemie
    Impakt faktor: 2.117, rok: 2009

    The ion/molecule reaction of [Pt(bipy – H)]+ (bipy = 2,2'-bipyridine) with dimethyl sulfide leads to the loss of ethene in the main reaction channel. This process corresponds to a formal dehydrosulfurization (DHS) accompanied by oxidative C–C coupling.
    Trvalý link: http://hdl.handle.net/11104/0173605