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BY-NC-ND 3.0 license Open Access Published by De Gruyter Open Access March 28, 2016

The role of the solvent in PMMA gel polymer electrolytes

  • J. Vondrák , M. Musil , M. Sedlaříková , R. Kořínek , K. Bartušek and A. Fedorková

Abstract

Ionic mobility and solvent vapor pressure were studied on gels containing sodium perchlorate, polymethylmethacrylate and sulfolane as a solvent. The excess of solvent increases markedly the mobility of ions and is indicated by solvent evaporation at elevated temperature. The solvent is bonded similarly as in the liquid solution of sodium salt. The heat of solvent evaporation from gels is near to that of pure solvents.

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Received: 2015-9-24
Accepted: 2016-1-23
Published Online: 2016-3-28

© 2016 J. Vondrák et al.

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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