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New Mn(II) and Cu(II) Complexes of Naphtaldimine Schiff Base Ligands: Synthesis, Characterization and Crystal Structures

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Abstract

Two new Schiff base ligands of HLBr and HLCl with the general formula C4H4-OHC6H3C=NCH2CH2X (X = Br, Cl) and their Mn(II) and Cu(II) complexes (1, 2, 3, and 4) are synthesized. Different characterization methods, such as the elemental analysis (CHN), 1H NMR and FT-IR spectroscopy, and the single crystal X-ray diffraction analysis are used to determine the composition, functional groups and crystal structures of the investigated compounds. The titled Schiff base ligands crystallize in the monoclinic system with the space group P21/c. The crystal packing of Schiff bases is stabilized by N-H⋯O and C-H⋯O hydrogen bonds. The Schiff bases are coordinated to Mn(II) and Cu(II) ion centers via two different donor atoms (nitrogen and oxygen) and form bis-chelate complexes M(LX)2 (1–4) in an approximately square planar coordination geometry. Complexes 1, 2, and 4 crystallize in the monoclinic system with the space group P21/c.

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Funding

We are grateful to the Damghan and Golestan University for he financial support of this work. The crystallography was supported by project 18-10504S of the Czech Science Foundation using instruments of the ASTRA lab established within the Operation program Prague Competitiveness — project CZ.2.16/3.1.00/24510.

Author information

Authors and Affiliations

  1. School of Chemistry, Damghan University, Damghan, Iran

    V. Tahmasebi & G. Grivani

  2. Institute of Physics Academy of Sciences of the Czech Republic, Prague, Czech Republic

    V. Eigner & M. Dusek

  3. Department of Chemistry, Faculty of Science, Golestan University, Gorgan, Iran

    A. D. Khalaji

Authors
  1. V. Tahmasebi
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  2. G. Grivani
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  3. V. Eigner
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  4. M. Dusek
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  5. A. D. Khalaji
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Corresponding author

Correspondence to G. Grivani.

Additional information

Additional Information

Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Center, CCDC Nos. 1533678, 1533679 for HLBr, HLCl, respectively and CCDC Nos. 1533680, 1533681, 1533682 for 1, 2, and 4 complexes, respectively. The data can be obtained free of charge on application to the Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, UK, fax: +44 1223 336 033, e-mail: deposit@ccdc.cam.ac.uk or http:www.ccdc.cam.ac.uk.

Conflict of Interests

The authors declare that they have no conflict of interests.

Text © The Author(s), 2020, published in Zhurnal Strukturnoi Khimii, 2020, Vol. 61, No. 1, pp. 62–70.

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Tahmasebi, V., Grivani, G., Eigner, V. et al. New Mn(II) and Cu(II) Complexes of Naphtaldimine Schiff Base Ligands: Synthesis, Characterization and Crystal Structures. J Struct Chem 61, 57–65 (2020). https://doi.org/10.1134/S0022476620010060

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  • DOI: https://doi.org/10.1134/S0022476620010060

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