Abstract
Normal-state transport properties (2–300 K) of the polycrystalline series ; ) were investigated by means of electrical resistivity, thermopower, Hall effect, and thermal conductivity measurements. The distortion of the valence-band structure by the In-induced resonant level (RL) has a profound influence on the evolution of the normal-state properties with and on the emergence of superconductivity evidenced by specific-heat measurements down to 0.35 K. In addition to a nearly 40-fold increase in the residual electrical resistivity on going from to 0.05, the thermopower shows a nonlinear, complex behavior as a function of both temperature and . While Hall measurements indicate a dominant holelike response across the entire composition and temperature ranges, changes sign below about 100 K and remains negative down to 5 K for . Additional measurements under magnetic fields of up to 14 T further shows that gradually shifts towards positive values, suggestive of a dominant holelike contribution to . Superconductivity emerges for at a critical temperature K, with increasing with to reach 1.73 K for . The variations in the superconducting parameters with , notably the specific-heat jump at , confirm the results reported in prior studies and suggests a nontrivial role of the RL on the electron-phonon coupling strength. The striking similarities between this series and the canonical resonant system provide an excellent experimental opportunity to gain a deeper understanding of the close interplay between resonant level, anomalous transport properties, and superconductivity.
6 More- Received 24 November 2021
- Revised 3 May 2022
- Accepted 5 August 2022
DOI:https://doi.org/10.1103/PhysRevB.106.075205
©2022 American Physical Society