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Characterization of Old Concrete from a Heritage Structure of Inousses Cluster of Islands

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Protection of Historical Constructions (PROHITECH 2021)

Abstract

In this work, the amorphous part of samples extracted from damaged concrete structural elements of a heritage church of Inousses cluster of islands (Greece) was studied. The samples were obtained from both the interior (dome) and the exterior (two walls and one column) of the church. The techniques employed include simultaneous thermal analysis and solid state nuclear magnetic resonance spectroscopy. Concrete degradation was mainly due to carbonation and it was more intense for the structural elements exposed directly to the environment (external walls and column). The components identified in the sample coming from the external column indicate that a different concrete composition was likely used for its construction.

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References

  • Andersen, M.D., Jakobsen, H.J., Skibsted, J.: A new aluminium-hydrate species in hydrated portland cements characterized by 27Al and 29Si MAS NMR spectroscopy. Cem. Concr. Res. 36, 3–17 (2006)

    Article  Google Scholar 

  • Bernard, E., Lothenbach, B., Rentsch, D., Pochard, I., Dauzères, A.: Formation of magnesium silicate hydrates (M-S-H). Phys. Chem. Earth 99, 142–157 (2017)

    Article  Google Scholar 

  • Bertolini, L., Carsana, M., Radaelli, E.: Conservation of historical reinforced concrete structures damaged by carbonation induced corrosion by means of electrochemical realkalisation. J. Cult. Herit. 9, 376–385 (2008)

    Article  Google Scholar 

  • Cao, Y., Gehlen, C., Angst, U., Wang, L., Wang, Z., Yao, Y.: Critical chloride content in reinforced concrete – an updated review considering Chinese experience. Cem. Concr. Res. 117, 58–68 (2019)

    Google Scholar 

  • Council of Europe: Convention for the Protection of the Architectural Heritage of Europe. European Treaty Series – No. 121 (1985)

    Google Scholar 

  • Engelhardt, G.: Silicon-29 NMR of Solid Silicates, in Encyclopedia of Nuclear Magnetic Resonance. John Wiley & Sons, Ltd. (2007)

    Google Scholar 

  • Földvári, M.: Handbook of Thermogravimetric System of Minerlas and its Use in Geological Practice. Geological Institute of Hungary (2011)

    Google Scholar 

  • Houston, J.R., Maxwell, R.S., Carroll, S.A.: Transformation of meta-stable calcium silicate hydrates to tobermotite: reaction kinetics and molecular structure from XRD and NMR spectroscopy. Geochem. Trans. 10, 1–14 (2009)

    Article  Google Scholar 

  • International Council on Monuments and Sites: Principles and Guidelines for Managing Tourism at Places of Cultural and Heritage Significance. ICOMOS International Cultural Tourism Committee (2002)

    Google Scholar 

  • Justnes, H., Meland, I., Bjoergum, J.O., Krane, J., Skjetne, T.: Nuclear magnetic resonance (NMR) – a powerful tool in cement and concrete research. Adv. Cem. Res. 3, 105–110 (1990)

    Article  Google Scholar 

  • Kunther, W., Dai, Z., Skibsted, J.: Thermodynamic modeling of hydrated white portland cement-metakaolin-limestone blends utilizing hydration kinetics from 29Si MAS NMR spectroscopy. Cem. Concr. Res. 86, 29–41 (2016)

    Article  Google Scholar 

  • Kunther, W., Lothenbach, B., Skibsted, J.: Influence of the Ca/Si ratio of the C-S-H phase on the interaction with sulfate ions and its impact on the ettringite crystallization pressure. Cem. Concr. Res. 69, 37–49 (2015)

    Article  Google Scholar 

  • Laimos, A.G.: Aignousa Our Homeland. K. Tsikopoulos Publishing (1965)

    Google Scholar 

  • Marcos, I., San-José, J.-T., Garmendia, L., Santamaría, A., Manso, J.M.: Central lessons from the historical analysis of 24 reinforced-concrete structures in Northern Spain. J. Cult. Herit. 20, 649–659 (2016)

    Article  Google Scholar 

  • Mendes, A., Gates, W.P., Sanjayan, J.G., Collins, F.: NMR, XRD, IR and synchrotron NEXAFS spectroscopic studies of OPC and OPC/slag cement paste hydrates. Mater. Struct. 44, 1773–1791 (2011)

    Article  Google Scholar 

  • Official Journal of the Hellenic Republic: Characterization of the Inousses Settlement of the Municipality of Inousses of the Prefecture of Chios and Determination of Special Terms and Limitations for Construction. Series D Issue No. 381, 27 May 1999. National Printing House (1999). (in Greek)

    Google Scholar 

  • Official Journal of the Hellenic Republic: Ratification of the Convention for the Protection of the Architectural Heritage of Europe. Series A Issue No. 61, 13 April 1992. National Printing House (1992). (in Greek)

    Google Scholar 

  • Papageorgiou, M., Pozoukidou, G.: The Traditional settlements of greece: planning and protection isuues. Geografies 24, 107–125 (2014). (in Greek)

    Google Scholar 

  • Scrivener, K.L., Snellings, R., Lothenbach, B.: A Practical Guide to Microstructural Analysis of Cementitious Materials. CRC Press, Taylor & Francis Group (2016)

    Google Scholar 

  • Sevelsted, T.F., Skibsted, J.: Carbonation of C-S-H and C-A-S-H samples studied by 13C, 27Al and 29Si MAS NMR spectroscopy. Cem. Concr. Res. 71, 56–65 (2015)

    Article  Google Scholar 

  • Skibsted, J., Henderson, E., Jakobsen, H.J.: Characterization of calcium aluminate phases in cements by 27Al MAS NMR spectroscopy. Inorg. Chem. 32, 1013–1027 (1993)

    Article  Google Scholar 

  • Sotiriadis, K., Mácová, P., Mazur, A.S., Tolstoy, P.M., Viani, A.: A solid state NMR in-situ infrared spectroscopy study on the setting reaction of magnesium sodium phosphate cement. J. Non-Cryst. Solids 498, 49–59 (2018)

    Article  Google Scholar 

  • Sun, G.K., Young, J.F., Kirkpatrick, R.J.: The role of Al in C-S-H: NMR, XRD, and compositional results for precipitated samples. Cem. Concr. Res. 36, 18–29 (2006)

    Article  Google Scholar 

  • Walkley, B., Provis, J.L.: Solid-state nuclear magnetic resonance spectroscopy of cements. Mater. Today Adv. 1, 100007 (2019)

    Article  Google Scholar 

  • Webb, G.A.: Annual Reports on NMR Spectroscopy 88. Academic Press (2016)

    Google Scholar 

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Acknowledgements

Solid state NMR spectroscopy experiments were implemented within the framework of the cooperation agreement between the St. Petersburg State University and the Institute of Theoretical and Applied Mechanics of the Czech Academy of Sciences.

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Correspondence to Konstantinos Aspiotis .

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Sotiriadis, K., Aspiotis, K., Mazur, A., Tolstoy, P., Badogiannis, E., Tsivilis, S. (2022). Characterization of Old Concrete from a Heritage Structure of Inousses Cluster of Islands. In: Vayas, I., Mazzolani, F.M. (eds) Protection of Historical Constructions. PROHITECH 2021. Lecture Notes in Civil Engineering, vol 209. Springer, Cham. https://doi.org/10.1007/978-3-030-90788-4_7

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  • DOI: https://doi.org/10.1007/978-3-030-90788-4_7

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  • Online ISBN: 978-3-030-90788-4

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