New dinuclear methoxo-bridged manganese(III) complex: Synthesis, characterization and usage as new precursor for synthesis of Mn.sub.2./sub.O.sub.3./sub. particles

0537580 - FZÚ 2021 RIV IR eng J - Článek v odborném periodiku
Khalaji, A.D. - Ghorbani, M. - Feizi, N. - Akbari, A. - Dušek, Michal - Eigner, Václav
New dinuclear methoxo-bridged manganese(III) complex: Synthesis, characterization and usage as new precursor for synthesis of Mn₂O₃ particles.
Journal of Sciences, Islamic Republic of Iran. Roč. 31, č. 1 (2020), s. 33-38. ISSN 1016-1104. E-ISSN 2345-6914
Grant CEP: GA ČR(CZ) GA15-12653S; GA MŠMT(CZ) LO1603
GRANT EU: European Commission(CZ) CZ.2.16/3.1.00/24510
Institucionální podpora: RVO:68378271
Klíčová slova: dinuclear * manganese(III) * Schiff base * crystal structure * Mn₂O₃ particles
Obor OECD: Condensed matter physics (including formerly solid state physics, supercond.)
Způsob publikování: Open access

New dinuclear methoxo-bridged manganese(III) complex [Mn2((MeObph)en)2Cl2(μ-CH3O)2] (1) was synthesized by template reaction of 2-hydroxy-4-methoxybenzophenone, 1,2-ethanediamine and MnCl2.6H2O with molar ration (1:1:1) in methanol as solvent. The title compound 1 was characterized by elemental analyses (CHN), Fourier Transform infrared spectroscopy (FT-IR) and single crystal X-ray diffraction. Finally, by calcination of 1 at 500 oC for 3 h, we prepared Mn2O3 particles and characterized by FT-IR, XRD and SEM.

Trvalý link: http://hdl.handle.net/11104/0315404