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Partial Oxidation of High-Boiling Hydrocarbon Mixtures in the Pilot Unit
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SYSNO ASEP 0440538 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Partial Oxidation of High-Boiling Hydrocarbon Mixtures in the Pilot Unit Author(s) Hanika, Jiří (UCHP-M) RID, ORCID, SAI
Lederer, J. (CZ)
Nečesaný, F. (CZ)
Poslední, W. (CZ)
Tukač, V. (CZ)
Veselý, Václav (UCHP-M) RID, SAISource Title Chemical Papers. - : Springer - ISSN 0366-6352
Roč. 68, č. 12 (2014), s. 1701-1706Number of pages 6 s. Language eng - English Country SK - Slovakia Keywords partial oxidation ; high-boiling hydrocarbons ; pilot plant Subject RIV CI - Industrial Chemistry, Chemical Engineering Institutional support UCHP-M - RVO:67985858 UT WOS 000344614200009 DOI 10.2478/s11696-014-0604-0 Annotation The reason for this investigation into the partial oxidation (POX) of high-boiling hydrocarbons with oxygen in the presence of water vapour was to ensure increased demand on hydrogen, which is essential for the deeper hydrorefining of petroleum oils to ensure better quality of motor fuels. The tests demonstrated the good performance of the pilot plant unit and also the reproducibility of the experiment. The investigation detected a significant impact of water vapour on the selectivity of the partial oxidation of high boiling-point hydrocarbons with regard to the composition of the exhaust gas. In addition, it was noted that the hydrogen content in the reaction product of the partial oxidation of the mixture of visbreaking distillate and residue diluted with pyrolysis fuel oil, achieved 50 %. The content of components in the gaseous product accorded well with a synthesis gas composition produced by the plant unit of the UNIPETROL RPA Co., designed and built under licence from the Shell Petroleum Co. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2015
Number of the records: 1