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Does Surface Roughness Amplify Wetting?
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SYSNO ASEP 0435409 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Does Surface Roughness Amplify Wetting? Author(s) Malijevský, Alexandr (UCHP-M) RID, ORCID, SAI Source Title Journal of Chemical Physics. - : AIP Publishing - ISSN 0021-9606
Roč. 141, č. 18 (2014), s. 184703Number of pages 10 s. Language eng - English Country US - United States Keywords density functional theory ; wetting ; roughness Subject RIV CF - Physical ; Theoretical Chemistry R&D Projects GA13-09914S GA ČR - Czech Science Foundation (CSF) Institutional support UCHP-M - RVO:67985858 UT WOS 000344847600034 DOI 10.1063/1.4901128 Annotation Any solid surface is intrinsically rough on the microscopic scale. In this paper, we study the effect of this roughness on the wetting properties of hydrophilic substrates. Macroscopic arguments, such as those leading to the well-known Wenzel’s law, predict that surface roughness should amplify the wetting properties of such adsorbents. We use a fundamental measure density functional theory to demonstrate the opposite effect from roughness for microscopically corrugated surfaces, i.e., wetting is hindered. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2015
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