Number of the records: 1

Photochemical Degradation of Polybrominated Diphenyl Ethers in Micro Photo-Reactor

SYSNO ASEP	0383286
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Photochemical Degradation of Polybrominated Diphenyl Ethers in Micro Photo-Reactor
Author(s)	Vajglová, Zuzana (UCHP-M)_{RID, ORCID, SAI} Veselý, M. (CZ) Křišťál, Jiří (UCHP-M)_RID Vychodilová, Hana (UCHP-M)_{RID, SAI} Tříska, Jan (UEK-B)_{RID, ORCID, SAI} Jiřičný, Vladimír (UCHP-M)_{RID, SAI}
Source Title	Procedia Engineering. - Amsterdam : Elsevier BV Roč. 42, SI (2012), s. 1378-1382
Number of pages	5 s.
Action	International Congress of Chemical and Process Engineering CHISA 2012 and 15th Conference PRES 2012 /20./
Event date	25.08.2012-29.08.2012
VEvent location	Prague
Country	CZ - Czech Republic
Event type	WRD
Language	eng - English
Country	NL - Netherlands
Keywords	polybrominated diphenyl ethers ; micro photo reactor ; debromination
Subject RIV	CI - Industrial Chemistry, Chemical Engineering
R&D Projects	GA104/09/0880 GA ČR - Czech Science Foundation (CSF)
Institutional support	UCHP-M - RVO:67985858 ; RVO:67179843 - RVO:67179843
UT WOS	000392862500141
EID SCOPUS	84886296812
DOI	10.1016/j.proeng.2012.07.530
Annotation	This work is focused on verification and comparison of the various dehalogenation methods of PBDE. In particular, the photochemical degradation reaction pathways of different selected congeners substituted with 1 to 10 bromines, in solvents are examined. Photochemical reaction is a non-invasive method with a high degradation potential. The photochemical reaction is conducted in batch or continuous reactors. Comparison of experimental results based on determination of individual reaction products shows the efficiency of the studied photochemical methods running in both reactor arrangements. New photochemical method employing the photochemical microreactor was investigated that has not been reported in the literature so far. The original experimental results confirm the significantly faster and deeper degradation rate of PBDE’s compared to the published results of the photocatalysis over nanoporous TiO2 in microwave field and the conventional photochemical reactors.
Workplace	Institute of Chemical Process Fundamentals
Contact	Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
Year of Publishing	2013

Number of the records: 1