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Geochemical distribution and mobility of heavy metals in sediments of urban streams affected by combined sewer overflows
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SYSNO ASEP 0360299 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Geochemical distribution and mobility of heavy metals in sediments of urban streams affected by combined sewer overflows Author(s) Hnaťuková, Petra (UH-J) RID, SAI, ORCID Source Title Journal of Hydrology and Hydromechanics. - : Ústav pro hydromechaniku AV ČR, v. v. i.. - : Ústav hydrológie SAV - ISSN 0042-790X
Roč. 59, č. 2 (2011), s. 85-94Number of pages 10 s. Language eng - English Country SK - Slovakia Keywords sediments ; heavy metals ; urban streams ; sequential extraction ; combined sewer overflows Subject RIV BK - Fluid Dynamics R&D Projects IAA200600902 GA AV ČR - Academy of Sciences of the Czech Republic (AV ČR) CEZ AV0Z20600510 - UH-J (2005-2011) UT WOS 000294700300002 DOI 10.2478/v10098-011-0007-7 Annotation Study was undertaken to assess the impact of combined sewer overflows (CSOs) on distribution and mobility of heavy metals in sediments of streams in Prague, Czech Republic. Contents of total and extractable heavy metals (Cu, Zn, Pb, Cd, Cr and Ni), mineralogical phases and other sediment properties were measured in 44 surficial sediment samples. The observed mobility order of metals was Cd > Zn > Ni > Cu > Pb > Cr. There was a considerable increase in Zn mobility and increase of Cu associated with the oxidisable fraction in the sediments below CSO discharges. Cd was revealed as the most mobile heavy metal with percentages of extraction of approximately 40–60% in acid soluble fraction. Pb was mainly found in reducible fraction associated with Fe/Mn (oxi)hydroxides. In terms of environmental significance, Cd and Zn can be particularly mobile and bioavailable under acidic conditions, because they are predominantly bound in labile fractions. Workplace Institute of Hydrodynamics Contact Soňa Hnilicová, hnilicova@ih.cas.cz, Tel.: 233 109 003 Year of Publishing 2012
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