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The Photoelectrocatalytic Properties of Thin TiO2 Electode
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SYSNO ASEP 0329704 Document Type C - Proceedings Paper (int. conf.) R&D Document Type The record was not marked in the RIV Title The Photoelectrocatalytic Properties of Thin TiO2 Electode Title Fotoelektokatalytické vlastnosti tenkých TiO2 elektrod Author(s) Morozová, Magdalena (UCHP-M) RID, SAI
Klusoň, Petr (UCHP-M) RID, ORCID, SAI
Krýsa, J. (CZ)
Šolcová, Olga (UCHP-M) RID, ORCID, SAISource Title Book of Abstracts. - Sofia : -, 2009 / Petrova G.P. ; Vayssilov G.N. - ISBN 978-954-323-558-2 Pages s. 138 Number of pages 1 s. Action International Symposium Advanced Micro- and Mesoporous Materials /3./ Event date 06.09.2009-09.09.2009 VEvent location Albena Country BG - Bulgaria Event type WRD Language eng - English Country BG - Bulgaria Keywords photoelectrocatalysis ; thin electrode ; photoelectrochemical behavior Subject RIV CC - Organic Chemistry R&D Projects GD203/08/H032 GA ČR - Czech Science Foundation (CSF) GA104/09/0694 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40720504 - UCHP-M (2005-2011) Annotation In this work we have studied the photoelectrochemical behavior of TiO2 anatase electrode in various electrolytes.The TiO2 thin film electrodes were prepared by repeated dip-coating of conductive ITO glass into a homogenous sol.Photoelectrochemical measurements were performed on a three-compartment electrochemical cell.The fundamental mechanism of photo excitation properties of layers consists in the generation of electron-hole pair.Due to a high recombination rate of the photogenerated holes and electrons the measured photo current is low.The recombination can be minimized by addition of oxidizable species.Holes may oxidize organic compounds while electrons migrate to conducting substrate.The measured value of generation photo current depends on adsorption properties of oxidizable substances in the solution, their concentration and the number of TiO2 layers deposited on electrode. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2010
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