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Model Aided Design of Gas-Lift Reactor for Oxidation Reaction with Fast Reversible Catalyst Deactivation
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SYSNO ASEP 0321118 Document Type C - Proceedings Paper (int. conf.) R&D Document Type Conference Paper Title Model Aided Design of Gas-Lift Reactor for Oxidation Reaction with Fast Reversible Catalyst Deactivation Title Využití modelu při designu gas-lift reaktoru pro oxidační reakci s rychlou reversibilní deaktivací katalyzátoru Author(s) Gogová, Zuzana (UCHP-M)
Hanika, Jiří (UCHP-M) RID, ORCID, SAISource Title Book of Abstracts. - Braga : -, 2008 / Ferreira E.C ; Mota M. - ISBN 978-972-97810-4-9 Pages s. 711 Number of pages 1 s. Publication form textový soubor - textový soubor Action International Chemical and Biological Engineering Conference - CHEMPOR 2008 /10./ Event date 04.09.2008-06.09.2008 VEvent location Braga Country PT - Portugal Event type EUR Language eng - English Country PT - Portugal Keywords gas-lift reactor ; glucose ; model Subject RIV CI - Industrial Chemistry, Chemical Engineering R&D Projects GD203/08/H032 GA ČR - Czech Science Foundation (CSF) CEZ AV0Z40720504 - UCHP-M (2005-2011) Annotation Tanks-in-series based model was applied to aid design of gas-lift reactor (GLR), where oxidation reaction along with catalyst reversible deactivation proceeds. Heterogeneously catalyzed wet air oxidation of glucose dissolved in aqueous alkaline solution served as model reaction. Commercial 2.8% Pd/C catalyst was used in this study. Its advantage is activity at mild conditions with high selectivity towards salt of gluconic acid. But it gets deactivated by the action of oxygen quickly during the reaction course. Multifunctional gas-lift reactor allows the desired reaction, as well as the catalyst reactivation. Optimal design of the gas-lift reactor makes it possible to keep high and stable activity of the catalyst. Workplace Institute of Chemical Process Fundamentals Contact Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227 Year of Publishing 2009
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