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Synthesis and Investigation of the Properties of Polymer-immobilized Silver- and Gold Nanoparticles
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SYSNO ASEP 0566393 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Synthesis and Investigation of the Properties of Polymer-immobilized Silver- and Gold Nanoparticles Author(s) Burkeyev, M. Z. (KZ)
Shibayeva, S. R. (KZ)
Khamitova, T. O. (KZ)
Plocek, Jiří (UACH-T) RID, ORCID, SAI
Nurmaganbetova, M. T. (KZ)
Kazhmuratova, A. T. (KZ)
Zhumagalieva, T. S. (KZ)Number of authors 7 Source Title Bulletin of the Karaganda University-Chemistry - ISSN 2518-718X
Roč. 2022, č. 107 SI (2022), s. 198-207Number of pages 10 s. Language eng - English Country KZ - Kazakhstan Keywords nanocomposites ; nanoparticles ; silver ; gold ; copolymer ; polypropylene glycol maleate phthalate with acrylic acid ; metal-polymer complex ; antimicrobial activity Subject RIV CA - Inorganic Chemistry OECD category Inorganic and nuclear chemistry Method of publishing Open access Institutional support UACH-T - RVO:61388980 UT WOS 000891829100018 DOI 10.31489/2022Ch3/3-22-6 Annotation Metal-polymer composites (MPC) based on copolymers of polypropylene glycol maleate phthalate with acrylic acid and metallic gold and silver were synthesized for the first time. The structure of nanocomposites is characterized with the help of microscopy and spectroscopy. Antimicrobial activity of novel metalpolymeric complexes based on silver and gold was studied. Metal-polymeric complexes were stabilized for the first time with polymeric matrix based on the copolymers of polypropyleneglycolmaleatephthalate with acrylic acid (p-PGMPh/AA:Ag, p-PGMPh/AA:Au). Obtained nanocomposites contain the nanoparticles of silver and gold of rhomboidal and cylindrical shapes with the sizes of 40-50 and 35-50 nm correspondingly. The size of more than 80 % of the nanoparticles are from 20 to 50 nm and has a spherical and rhombic shape. For determination of antimicrobial activity of the MPC the reference test-microorganisms such as facultativeanaerobe gram-positive Staphylococcus aureus, aerobic gram-positive spore-forming Bacillus subtilis, gramnegative facultative anaerobe of Escheri.hia coli, aerobic Pseudomonas aeruginosa and yeast fungi.andida albicans have been used. The resulting nanocomposites are stable and promising for the creation of new photochromic and nonlinear optical materials, as well as for using in medicine in the development of antiseptic and antimicrobial materials that are needed during a pandemic. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2023 Electronic address https://hdl.handle.net/11104/0338221
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