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Solvent-assisted synthesis of supramolecular-assembled graphitic carbon nitride for visible light induced hydrogen evolution - a review

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    SYSNO ASEP0547911
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleSolvent-assisted synthesis of supramolecular-assembled graphitic carbon nitride for visible light induced hydrogen evolution - a review
    Author(s) Dolai, Susmita (UCHP-M) SAI
    Kumar, S. (IN)
    Bhunia, K. (IN)
    Klusoň, Petr (UCHP-M) RID, ORCID, SAI
    Stavárek, Petr (UCHP-M) RID, ORCID, SAI
    Pittermanová, Anna (UCHP-M)
    Article numbere202101299
    Source TitleChemCatChem. - : Wiley - ISSN 1867-3880
    Roč. 14, č. 4 (2022)
    Number of pages21 s.
    Languageeng - English
    CountryDE - Germany
    Keywordscalcination ; graphitic carbon nitride ; hydrogen bonding
    Subject RIVCI - Industrial Chemistry, Chemical Engineering
    OECD categoryChemical process engineering
    R&D ProjectsSS02030008 GA TA ČR - Technology Agency of the Czech Republic (TA ČR)
    Method of publishingLimited access
    Institutional supportUCHP-M - RVO:67985858
    UT WOS000719619800001
    EID SCOPUS85119142621
    DOI10.1002/cctc.202101299
    AnnotationMany graphitic carbon nitride (g-C 3 N 4 )-based photocatalysts have attracted a significant interest because of the unique arrangement of carbon and nitrogen atoms. Changeable morphologies with tuneable bandgap of g-C 3 N 4 materials were used in many applications including batteries, photovoltaics, photocatalysts, sensors, etc. This review focuses on the recent progress in the solvent assisted supramolecular-assembled carbon nitride preparation for visible light induced hydrogen evolution from water. The synthesis involves tailoring the supramolecular assembly from different monomers followed by calcination. Different types of non-covalent interactions between the monomers have been explained. In addition, the crucial role of solvent has been re-counted in terms of the alteration of the structural morphology of assemblies. The mechanistic pathways of interaction in the formation of supramolecular assemblies have been also documented by molecular dynamics simulation. Finally, visible light triggered hydrogen evolution has been demonstrated along with discussion on challenges and future research direction.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2023
    Electronic addresshttp://hdl.handle.net/11104/0324492
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