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Role of pH in the synthesis and growth of gold nanoparticles using L-asparagine: a combined experimental and simulation study

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    SYSNO ASEP0546894
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleRole of pH in the synthesis and growth of gold nanoparticles using L-asparagine: a combined experimental and simulation study
    Author(s) Báez-Cruz, R. (DE)
    Baptista, L. A. (DE)
    Ntim, S. (DE)
    Manidurai, P. (CL)
    Espinoza Herrera, Shirly J. (FZU-D) ORCID
    Ramanan, C. (DE)
    Cortes-Huerto, R. (DE)
    Sulpizi, M. (DE)
    Number of authors8
    Article number254005
    Source TitleJournal of Physics-Condensed Matter. - : Institute of Physics Publishing - ISSN 0953-8984
    Roč. 33, č. 25 (2021)
    Number of pages11 s.
    Languageeng - English
    CountryGB - United Kingdom
    Keywordsgold nanoparticles ; green-synthesis ; L-asparagine ; Raman spectroscopy ; density functional theory ; molecular dynamics
    Subject RIVJJ - Other Materials
    OECD categoryNano-materials (production and properties)
    R&D ProjectsEF16_019/0000789 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    EF15_003/0000447 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    Research InfrastructureELI Beamlines III - 90141 - Fyzikální ústav AV ČR, v. v. i.
    Method of publishingOpen access
    Institutional supportFZU-D - RVO:68378271
    UT WOS000655292800001
    EID SCOPUS85107086793
    DOI10.1088/1361-648X/abf6e3
    AnnotationThe use of biomolecules as capping and reducing agents in the synthesis of metallic nanoparticles constitutes a promising framework to achieve desired functional properties with minimal toxicity. The system's complexity and the large number of variables involved represent a challenge for theoretical and experimental investigations aiming at devising precise synthesis protocols. In this work, we use L-asparagine (Asn), an amino acid building block of large biomolecular systems, to synthesise gold nanoparticles (AuNPs) in aqueous solution at controlled pH. The use of Asn offers a primary system that allows us to understand the role of biomolecules in synthesising metallic nanoparticles. Our results indicate that AuNPs synthesised in acidic (pH 6) and basic (pH 9) environments exhibit somewhat different morphologies.
    WorkplaceInstitute of Physics
    ContactKristina Potocká, potocka@fzu.cz, Tel.: 220 318 579
    Year of Publishing2022
    Electronic addresshttp://hdl.handle.net/11104/0323330
Number of the records: 1  

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