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Time-resolved Fourier transform infrared emission spectroscopy of CO Delta v=1 and Delta v=2 extended bands in the ground X-1 Sigma+ state produced by formamide glow discharge

  1. 1.
    SYSNO ASEP0542619
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleTime-resolved Fourier transform infrared emission spectroscopy of CO Delta v=1 and Delta v=2 extended bands in the ground X-1 Sigma+ state produced by formamide glow discharge
    Author(s) Pastorek, Adam (UFCH-W) ORCID
    Civiš, Svatopluk (UFCH-W) RID, ORCID, SAI
    Clark, V. H. J. (GB)
    Yurchenko, S. N. (GB)
    Ferus, Martin (UFCH-W) ORCID, RID
    Article number107521
    Source TitleJournal of Quantitative Spectroscopy and Radiative Transfer. - : Elsevier - ISSN 0022-4073
    Roč. 262, MAR 2021 (2021)
    Number of pages9 s.
    Languageeng - English
    CountryGB - United Kingdom
    KeywordsCarbon monoxide ; Formamide ; ftir ; Glow discharge ; Spectroscopy ; Time resolved
    Subject RIVCF - Physical ; Theoretical Chemistry
    OECD categoryPhysical chemistry
    R&D ProjectsEF16_019/0000778 GA MŠMT - Ministry of Education, Youth and Sports (MEYS)
    GA19-03314S GA ČR - Czech Science Foundation (CSF)
    Method of publishingLimited access
    Institutional supportUFCH-W - RVO:61388955
    UT WOS000642457300013
    EID SCOPUS85099690311
    DOI10.1016/j.jqsrt.2021.107521
    AnnotationThis paper presents an extension to our knowledge of Delta v = 1 and Delta v = 2 bands of carbon monoxide in the ground state, measured by Fourier transform infrared spectroscopy of glow discharge of formamidenitrogen mixture. Lines in declared bands are measured up to v = 30 for Delta v = 1 and up to v = 24 for Delta v = 2 band, by use of both InSb and MCT detectors, which have not been measured in the laboratory before. Dunham parameters obtained by fitting our lines are presented as well as comparison to other authors. The paper also demonstrates the interesting impossibility of sufficient population of Delta v = 2 band of CO when only pure CO is used in the glow discharge, instead of formamide-based mixture. Additionally, we present a non-LTE model to describe the intensity pattern of the Delta v = 1 and the Delta v = 2 bands of (CO)-C-12-O-16 experimental spectra by simulating the corresponding non-LTE vibrational populations of CO. (C) 2021 Published by Elsevier Ltd.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2022
    Electronic addresshttp://hdl.handle.net/11104/0320002
Number of the records: 1  

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