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Effect of additives on cadmium chemical vapor generation and reliable quantification of generation efficiency
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SYSNO ASEP 0542264 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Effect of additives on cadmium chemical vapor generation and reliable quantification of generation efficiency Author(s) Sagapova, Linda (UIACH-O) ORCID
Musil, Stanislav (UIACH-O) RID, ORCID
Kodríková, Barbora (UIACH-O)
Svoboda, Milan (UIACH-O) RID, ORCID
Kratzer, Jan (UIACH-O) RID, ORCIDNumber of authors 5 Article number 338601 Source Title Analytica Chimica Acta. - : Elsevier - ISSN 0003-2670
Roč. 1168, JUL (2021)Number of pages 11 s. Publication form Print - P Language eng - English Country NL - Netherlands Keywords cadmium ; volatile species generation ; generation efficiency Subject RIV CB - Analytical Chemistry, Separation OECD category Analytical chemistry R&D Projects GA18-01116S GA ČR - Czech Science Foundation (CSF) Method of publishing Limited access Institutional support UIACH-O - RVO:68081715 UT WOS 000651222000002 EID SCOPUS 85105575322 DOI 10.1016/j.aca.2021.338601 Annotation Chemical vapor generation (CVG) of cadmium was optimized and effect of several modifiers on analytical performance was studied. The highest efficiency, between 60 and 70%, was reached in the presence of Cr3+/KCN and Ti4+/KCN while 19% was achieved in Co2+/thiourea/ascorbic acid environment. Highly irreproducible results with low CVG efficiency ranging from 2.5 to 15% were reached in the absence of any additives. Workplace Institute of Analytical Chemistry Contact Iveta Drobníková, drobnikova@iach.cz, Tel.: 532 290 234 Year of Publishing 2022 Electronic address http://hdl.handle.net/11104/0319721
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