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Dioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol

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    SYSNO ASEP0541903
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleDioxygen splitting at room temperature over distant binuclear transition metal centers in zeolites for direct oxidation of methane to methanol
    Author(s) Mlekodaj, Kinga (UFCH-W) RID, ORCID
    Lemishka, Mariia (UFCH-W) RID, ORCID
    Sklenák, Štěpán (UFCH-W) RID, ORCID, SAI
    Dědeček, Jiří (UFCH-W) RID, ORCID
    Tabor, Edyta (UFCH-W) RID, ORCID
    Source TitleChemical Communications. - : Royal Society of Chemistry - ISSN 1359-7345
    Roč. 57, č. 28 (2021), s. 3472-3475
    Number of pages4 s.
    Languageeng - English
    CountryGB - United Kingdom
    Keywordszeolites ; oxidation ; methane ; methanol
    Subject RIVCF - Physical ; Theoretical Chemistry
    OECD categoryPhysical chemistry
    R&D ProjectsGA17-00742S GA ČR - Czech Science Foundation (CSF)
    GA19-02901S GA ČR - Czech Science Foundation (CSF)
    Method of publishingLimited access
    Institutional supportUFCH-W - RVO:61388955
    UT WOS000637108400007
    EID SCOPUS85103733152
    DOI10.1039/d1cc00909e
    AnnotationHere we demonstrate for the first time the splitting of dioxygen at RT over distant binuclear transition metal (M = Ni, Mn, and Co) centers stabilized in ferrierite zeolite. Cleaved dioxygen directly oxidized methane to methanol, which can be released without the aid of an effluent to the gas phase at RT.
    WorkplaceJ. Heyrovsky Institute of Physical Chemistry
    ContactMichaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196
    Year of Publishing2022
    Electronic addresshttp://hdl.handle.net/11104/0319400
Number of the records: 1  

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