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Zeolite constructor kit: Design for catalytic applications
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SYSNO ASEP 0506557 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Zeolite constructor kit: Design for catalytic applications Author(s) Opanasenko, Maksym (UFCH-W) RID, ORCID Source Title Catalysis Today. - : Elsevier - ISSN 0920-5861
Roč. 304, APR 2018 (2018), s. 2-11Number of pages 10 s. Language eng - English Country NL - Netherlands Keywords post-synthesis incorporation ; mfi zeolite ; mesoporous zeolites ; zsm-5 zeolites ; textural properties ; acidic properties ; metal-clusters Subject RIV CF - Physical ; Theoretical Chemistry OECD category Physical chemistry Method of publishing Limited access Institutional support UFCH-W - RVO:61388955 UT WOS 000425179000002 EID SCOPUS 85028622793 DOI 10.1016/j.cattod.2017.08.026 Annotation Pure microporosity of conventional zeolites is a disadvantage for the processes required enhanced accessibility that can be overcome by the design of mesoporous or hierarchical zeolites. Approaches for development of additional porosity in zeolite materials including diverse bottom-up and top-down strategies are considered and compared in this paper. Zeolites are presented as construction kits to produce more open and hence active materials for catalytic applications. This review focuses on the understanding of advantages and limitations of each synthesis approach. The advances in design of hierarchical materials as catalysts are exemplified by comparison with bulk analogues. The possibilities for encapsulation of nanoparticles in microporous or hierarchical zeolitic frameworks are also assessed. Workplace J. Heyrovsky Institute of Physical Chemistry Contact Michaela Knapová, michaela.knapova@jh-inst.cas.cz, Tel.: 266 053 196 Year of Publishing 2020 Electronic address http://hdl.handle.net/11104/0297791
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