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The Role of Titania Layers in Decomposition of Endocrine Disruptors under UV Light.

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    SYSNO ASEP0490479
    Document TypeJ - Journal Article
    R&D Document TypeJournal Article
    Subsidiary JČlánek ve WOS
    TitleThe Role of Titania Layers in Decomposition of Endocrine Disruptors under UV Light.
    Author(s) Šolcová, Olga (UCHP-M) RID, ORCID, SAI
    Spáčilová, Lucie (UCHP-M) RID, SAI
    Caklová, Magdalena (UCHP-M) RID, SAI
    Dytrych, Pavel (UCHP-M) RID, ORCID, SAI
    Maléterová, Ywetta (UCHP-M) RID, ORCID, SAI
    Bumba, Jakub (UCHP-M) SAI
    Kaštánek, František (UCHP-M) RID, SAI, ORCID
    Hanika, Jiří (UCHP-M) RID, ORCID, SAI
    Source TitleJournal of Sol-Gel Science and Technology. - : Springer - ISSN 0928-0707
    Roč. 88, č. 1 (2018), s. 22-32
    Number of pages11 s.
    Languageeng - English
    CountryNL - Netherlands
    Keywordstitanium dioxide ; photocatalysis ; photolysis
    Subject RIVCI - Industrial Chemistry, Chemical Engineering
    OECD categoryChemical process engineering
    R&D ProjectsTA04020700 GA TA ČR - Technology Agency of the Czech Republic (TA ČR)
    Institutional supportUCHP-M - RVO:67985858
    UT WOS000445914600004
    EID SCOPUS85045436844
    DOI10.1007/s10971-018-4654-6
    AnnotationDegradation of three different endocrine disruptors (EDs) was thoroughly studied on prepared durable thin layers of titanium dioxide with an anatase crystalline structure. Specially constructed laboratory reactors bringing information on all individual processes (photolysis, photo-catalysis, sorption) involved in decomposition of the studied EDs (17 α-ethynylestradiol, bisphenol A and 4-nonylphenol) were applied. It was found that photolytic removal of EDs is the fastest degradation process. It was verified that individual degradation processes (photolysis and photocatalysis) showed a significantly different influence on toxicity of resulting solutions. During the photolytic process, EDs degradation caused increasing toxicity contrary to the photocatalytic process. Obtained results were corroborated by a mathematical model, which showed that a limitation step for photocatalysis is a sorption and for photolysis a toxicity of resulting products.
    WorkplaceInstitute of Chemical Process Fundamentals
    ContactEva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
    Year of Publishing2019
Number of the records: 1  

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