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Red-clay ceramic powders as geopolymer precursors: Consideration of amorphous portion and CaO content
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SYSNO ASEP 0489350 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Red-clay ceramic powders as geopolymer precursors: Consideration of amorphous portion and CaO content Author(s) Keppert, M. (CZ)
Vejmelková, E. (CZ)
Bezdička, Petr (UACH-T) SAI, RID, ORCID
Doleželová, M. (CZ)
Čáchová, M. (CZ)
Scheinherrová, L. (CZ)
Pokorný, J. (CZ)
Vyšvařil, M. (CZ)
Rovnaníková, P. (CZ)
Černý, R. (CZ)Number of authors 10 Source Title Applied Clay Science. - : Elsevier - ISSN 0169-1317
Roč. 161, SEP (2018), s. 82-89Number of pages 8 s. Language eng - English Country NL - Netherlands Keywords Amorphous content ; Calcium oxide ; Composition ; Geopolymers ; Red-clay ceramics Subject RIV CA - Inorganic Chemistry OECD category Inorganic and nuclear chemistry Institutional support UACH-T - RVO:61388980 UT WOS 000436916600011 EID SCOPUS 85045702890 DOI 10.1016/j.clay.2018.04.019 Annotation Geopolymers are conventionally prepared from metakaolin, fly ash, or blast furnace slag. In this paper, geopolymer synthesis using two different red-clay ceramic powders and a varying amount of Na2O/SiO2 activator is presented. Experimental results show that despite of the high content of crystalline minerals and lower concentration of amorphous matter, both tested precursors enable to prepare geopolymers with satisfactory mechanical properties. The discussion of measured values of compressive strength with respect to SiO2 /Al2O3 and Al2O3 /(Na2O + K2O) ratios in the prepared geopolymer mixes reveals that the consideration of only amorphous portion of ceramics is appropriate. A higher content of CaO in the precursor is found to cause a broader pore size distribution and higher porosity of resulting geopolymers, which is due to the formation of calcium silicate hydrates. Workplace Institute of Inorganic Chemistry Contact Jana Kroneislová, krone@iic.cas.cz, Tel.: 311 236 931 Year of Publishing 2019
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