Photocatalytic radical addition of 1,1,2,2-tetrafluoro-1-iodoethane to alkenes

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SYSNO ASEP	0485472
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Ostatní články
Title	Photocatalytic radical addition of 1,1,2,2-tetrafluoro-1-iodoethane to alkenes
Author(s)	Voltrová, Svatava (UOCHB-X)_{RID, ORCID} Beier, Petr (UOCHB-X)_{RID, ORCID}
Source Title	Fluorine notes - ISSN 2071-4807 Roč. 6, č. 115 (2017)
Number of pages	7 s.
Language	eng - English
Country	RU - Russian Federation
Keywords	photocatalysis ; radical addition ; Rhodamine B ; Eosin Y ; tetrafluoroiodoethane ; LED
Subject RIV	CC - Organic Chemistry
OECD category	Organic chemistry
Institutional support	UOCHB-X - RVO:61388963
DOI	10.17677/fn20714807.2017.06.02
Annotation	Photocatalytic radical addition and addition-elimination reactions of terminal alkenes with 1,1,2,2-tetrafluoro-1-iodoethane under a blue LED light irradiation are reported. The photoredox catalysis with Rhodamine B or Eosin Y provided the corresponding 1,1,2,2-tetrafluoro-4-iodoalkanes or 1,1,2,2-tetrafluoroalkenes, respectively, in good yields. The obtained iododerivatives were successfully hydrodeiodinated to form saturated 1,1,2,2-tetrafluoroalkanes.
Workplace	Institute of Organic Chemistry and Biochemistry
Contact	asep@uochb.cas.cz ; Kateřina Šperková, Tel.: 232 002 584 ; Viktorie Chládková, Tel.: 232 002 434
Year of Publishing	2018
Electronic address	http://notes.fluorine1.ru/public/2017/6_2017/article_2.html

Number of the records: 1