Number of the records: 1

Synthesis of new cobalt aluminophosphate framework by opening a cobalt methylphosphonate layered material

SYSNO ASEP	0482887
Document Type	J - Journal Article
R&D Document Type	Journal Article
Subsidiary J	Článek ve WOS
Title	Synthesis of new cobalt aluminophosphate framework by opening a cobalt methylphosphonate layered material
Author(s)	Zaarour, M. (FR) Pérez, O. (FR) Boullay, P. (FR) Martens, J. (DE) Mihailova, B. (DE) Karaghiosoff, K. (DE) Palatinus, Lukáš (FZU-D)_{RID, ORCID} Mintova, S. (FR)
Number of authors	8
Source Title	CrystEngComm. - : Royal Society of Chemistry - ISSN 1466-8033 Roč. 19, č. 34 (2017), s. 5100-5105
Number of pages	6 s.
Publication form	Online - E
Language	eng - English
Country	GB - United Kingdom
Keywords	cobalt aluminophosphate ; cobalt methylphosphonate ; layered materials ; crystallic structure ; X-ray diffraction
Subject RIV	BM - Solid Matter Physics ; Magnetism
OECD category	Condensed matter physics (including formerly solid state physics, supercond.)
Institutional support	FZU-D - RVO:68378271
UT WOS	000409204400017
EID SCOPUS	85028758072
DOI	10.1039/c7ce01129f
Annotation	A highly stable, cobalt rich, template free Co–AlPO material was prepared by opening the structure of cobalt methylphosphonate layered material under hydrothermal treatment in the presence of aluminium. CoMeP serves as the structure directing unit favoring the preferential formation of Al–O–P bonds, thus connecting the neighboring layers, which results in alternating Co–P and Al stacks. The new Co–AlPO material is monoclinic, and it is built of 12 membered ellipsoidal channels running along the crystallographic c-axis containing confined water molecules and another 6 membered hexagonal channels along the a-axis, where Co2+ cations are occasionally found. The formation of Al–O–P bonds was proved by FTIR, Raman spectroscopy, and single crystal X-ray diffraction.
Workplace	Institute of Physics
Contact	Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579
Year of Publishing	2018

Number of the records: 1