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Stereoselective Hydrogenation of Methylacetoacetate in Microfluidic Chip Reactor in Presence of [N8222][Tf2N] Ionic Liquid.

SYSNO ASEP	0480381
Document Type	C - Proceedings Paper (int. conf.)
R&D Document Type	The record was not marked in the RIV
Title	Stereoselective Hydrogenation of Methylacetoacetate in Microfluidic Chip Reactor in Presence of [N8222][Tf2N] Ionic Liquid.
Author(s)	Hejda, Stanislav (UCHP-M)_{RID, ORCID, SAI} Klusoň, Petr (UCHP-M)_{RID, ORCID, SAI} Stavárek, Petr (UCHP-M)_{RID, ORCID, SAI} Pěnkavová, Věra (UCHP-M)_{RID, ORCID, SAI} Vychodilová, Hana (UCHP-M)_{RID, SAI} Bendová, Magdalena (UCHP-M)_{RID, ORCID, SAI}
Source Title	Final Programme & Book of Abstracts. - Veszprém : OOK-Press, 2017 - ISBN 978-615-5270-41-3
Pages	s. 49
Number of pages	1 s.
Publication form	Print - P
Action	Conference on Frontiers in Organic Synthesic Technology /6./
Event date	18.10.2017 - 20.10.2017
VEvent location	Budapest
Country	HU - Hungary
Event type	EUR
Language	eng - English
Country	HU - Hungary
Keywords	stereoselectivity ; microfluidic chip ; chiral catalyst
Subject RIV	CI - Industrial Chemistry, Chemical Engineering
OECD category	Chemical process engineering
R&D Projects	GA15-04790S GA ČR - Czech Science Foundation (CSF)
Institutional support	UCHP-M - RVO:67985858
Annotation	In this study, we focused on the application of a microfluidic chip reactor (MR, Chemtrix 3222 and 3223) to the stereoselective hydrogenation of methylacetoacetate (MAA) to isomeric (R)-(+) or (S)-(-)-methyl-3-hydroxybutanoates (MHB) over a chiral ([RuCl((R)-BINAP)(p-cymene)]Cl) complex immobilized in the mixed [N8222][Tf2N]/methanol/water solvent phase.
Workplace	Institute of Chemical Process Fundamentals
Contact	Eva Jirsová, jirsova@icpf.cas.cz, Tel.: 220 390 227
Year of Publishing	2018

Number of the records: 1