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Reactions of copper(II), nickel(II), and zinc(II) acetates with a new water-soluble 4-phenylthiosemicarbazone Schiff base ligand: synthesis, characterization, unexpected cyclization, antimicrobial, antioxidant, and anticancer activities
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SYSNO ASEP 0473836 Document Type J - Journal Article R&D Document Type Journal Article Subsidiary J Článek ve WOS Title Reactions of copper(II), nickel(II), and zinc(II) acetates with a new water-soluble 4-phenylthiosemicarbazone Schiff base ligand: synthesis, characterization, unexpected cyclization, antimicrobial, antioxidant, and anticancer activities Author(s) Hosseini-Yazdi, S.A. (IR)
Mirzaahmadi, A. (IR)
Khandar, A.A. (IR)
Eigner, Václav (FZU-D) RID, ORCID
Dušek, Michal (FZU-D) RID, ORCID, SAI
Mahdavi, M. (IR)
Soltani, S. (IR)
Lotfipour, F. (IR)
White, J. (AU)Number of authors 9 Source Title Polyhedron. - : Elsevier - ISSN 0277-5387
Roč. 124, Mar (2017), s. 156-165Number of pages 10 s. Language eng - English Country GB - United Kingdom Keywords antimicrobial ; antioxidant ; cytotoxicity ; thiosemicarbazone ; water-soluble Schiff base Subject RIV BM - Solid Matter Physics ; Magnetism OECD category Condensed matter physics (including formerly solid state physics, supercond.) R&D Projects GA15-12653S GA ČR - Czech Science Foundation (CSF) LO1603 GA MŠMT - Ministry of Education, Youth and Sports (MEYS) Institutional support FZU-D - RVO:68378271 UT WOS 000397834900018 EID SCOPUS 85009453076 DOI 10.1016/j.poly.2016.12.004 Annotation A new Schiff base thiosemicarbazone ligand with aqueous solubility, namely, sodium 3-{[(anilinocarbonothioyl)hydrazono]methyl}-4-hydroxy benzene sulfonate (NaH2L) was synthesized by condensation of 4-phenylthiosemicarbazide and sodium salicylaldehyde-5-sulfonate (NaSalSO3) and characterized by elemental analysis, spectroscopic methods (UV–Vis, 1H NMR, FTIR) and electrospray ionization mass spectrometry. A co-crystal (Na(H2L)·Na(SalSO3)) of NaH2L and NaSalSO3 was prepared which confirmed the expected structure of the ligand. Reactions of NaH2L·0.5H2O with copper(II), nickel(II), and zinc(II) acetates were investigated under reflux conditions in methanol to produce following complexes [Cu2(Lcycl)2(H2O)2]·2H2O (CuLcycl), Ni(HL)(H2O)3 (NiL), and Zn(HL)(H2O)3 (ZnL). Workplace Institute of Physics Contact Kristina Potocká, potocka@fzu.cz, Tel.: 220 318 579 Year of Publishing 2018
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